Lipoprotein metabolism

 

Lipoprotein Metabolism & Hyperlipidemias

Apolipoprotein / Enzyme Primary Location High-Yield Biochemical Function
Apo B-48 Chylomicrons, Remnants Mediates chylomicron secretion from enterocytes into lymphatics. Lacks the LDL-receptor binding domain.
Apo B-100 VLDL, IDL, LDL Mediates hepatic secretion of VLDL. Acts as the primary structural ligand for the LDL Receptor.
Apo C-II Chylomicrons, VLDL, HDL An essential cofactor that activates Lipoprotein Lipase (LPL) to hydrolyze core triglycerides.
Apo E All except LDL Mediates remnant uptake by driving binding to hepatic LRP and LDL receptors.
Apo A-I HDL Activates LCAT (Lecithin-cholesterol acyltransferase) to esterify cholesterol for reverse transport.
CETP Plasma Shunt Protein Mediates transfer of cholesteryl esters from HDL to VLDL/IDL/LDL in exchange for triglycerides.
PCSK9 Hepatic Extracellular Binds to the LDL receptor and targets it for lysosomal degradation, reducing clearance.
High-Yield Familial Dyslipidemias:

  • Type I – Familial Chylomicronemia: Autosomal recessive deficiency in LPL or Apo C-II. Chylomicrons build up, driving sky-high plasma triglycerides. Presents with recurrent eruptive xanthomas, milky plasma, and acute pancreatitis. No increased risk for atherosclerosis.
  • Type IIa – Familial Hypercholesterolemia: Autosomal dominant defect or absence of functional LDL Receptors or mutant Apo B-100. Serum LDL levels skyrocket. Presents with premature coronary artery disease, tendon xanthomas (Achilles), and corneal arcus.
  • Type III – Familial Dysbetalipoproteinemia: Patient is homozygous for the Apo E2 isoform, which binds poorly to hepatic receptors. Chylomicron remnants and IDL accumulate in circulation. Key markers: palmar xanthomas and premature cardiovascular disease.
  • Abetalipoproteinemia Pathology: Autosomal recessive loss-of-function mutation in the Microsomal Triglyceride Transfer Protein (MTP). Enterocytes cannot load Apo B-48 and hepatocytes cannot load Apo B-100. Chylomicrons and VLDL are completely absent from plasma. Biopsy shows enterocytes packed with lipids; clinically presents with malabsorption, steatorrhea, acanthocytosis (spur cells), and retinitis pigmentosa.